Calendar Aging Effect on the Open Circuit Voltage of Lithium-Ion Battery

Lithium Ion Battery Anode Aging Mechanisms

Degradation mechanisms such as lithium plating, growth of the passivated surface film layer on the electrodes and loss of both recyclable lithium ions and electrode material adversely affect the longevity of the lithium ion battery. The anode electrode is very vulnerable to these degradation mechanisms. In this paper, the most common aging mechanisms occurring at the anode during the operation ...

Cubic Spline Regression for the Open-Circuit Potential Curves of a Lithium-Ion Battery

A cubic spline regression model was used to fit the experimental open-circuit potential ~OCP! curves of two intercalation electrodes of a lithium-ion battery. All the details of an OCP curve were accurately predicted by the resulting model. The number of regression intervals used to fit an OCP curve was determined in a way such that in each regression interval the OCP exhibits a profile predict...

Superconcentrated electrolytes for a high-voltage lithium-ion battery

Finding a viable electrolyte for next-generation 5 V-class lithium-ion batteries is of primary importance. A long-standing obstacle has been metal-ion dissolution at high voltages. The LiPF6 salt in conventional electrolytes is chemically unstable, which accelerates transition metal dissolution of the electrode material, yet beneficially suppresses oxidative dissolution of the aluminium current...

An Open-circuit-voltage Model of Lithium-ion Batteries for Effective Incremental Capacity Analysis

Open-Circuit-Voltage (OCV) is an essential part of battery models for state-of-charge (SOC) estimation. In this paper, we propose a new parametric OCV model, which considers the staging phenomenon during the lithium intercalation/deintercalation process. Results show that the new parametric model improves SOC estimation accuracy compared to other existing OCV models. Moreover, the model is show...

Modeling The Lithium-ion Battery